Nickel-catalysed carboxylation of organoboronates.
نویسندگان
چکیده
A nickel/N-heterocyclic carbene (NHC) catalysed carboxylation of aryl-, heteroaryl- and alkenylboronates, affording the corresponding carboxylic acids, has been developed. This transformation proceeds under one atmosphere of CO2 with a broad range of substrates and exhibits good functional group compatibility.
منابع مشابه
CARBON DIOXIDE OR BICARBONATE AS SUBSTRATE OF NICOTINAMIDE-ADENINE DINUCLEOTIDE PHOSPHATE-LINKED ISOCITRATE DEHYDROGENASE AND 'MALIC' ENZYME By K. DALZIEL
1. A simple kinetic method was devised to show whether dissolved CO2 orHCO3ion is the substrate in enzyme-catalysed carboxylation reactions. 2. The timecourse of the reductive carboxylation of 2-oxoglutarate by NADPH, catalysed by isocitrate dehydrogenase, was studied by a sensitive fluorimetric method at pH 7-3 and pH 6-4, with large concentrations of substrate and coenzyme and small carbon di...
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ورودعنوان ژورنال:
- Chemical communications
دوره 50 59 شماره
صفحات -
تاریخ انتشار 2014